Active Species in Anionic Polymerization of Phenylbutadienes —Reactivity of Model Anions—
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چکیده
منابع مشابه
Anionic polymerization mechanism of acrylonitrile trimer anions: key branching point between cyclization and chain propagation.
A cluster anion of vinyl compounds in the gaseous phase has served as one of the simplest microscopic models of the initial stages of anionic polymerization. Herein, we describe our investigations into the initial stage mechanisms of anionic polymerization of acrylonitrile (AN; CH2═CHCN) trimer anions. While the cyclic oligomer is found in mass and photoelectron spectroscopic studies of (AN)3(-...
متن کاملSynthesis of Polyamide 6 by Anionic Polymerization of ε-Caprolactam in an Internal Mixer: Effect of Polymerization Reaction Time
The main objective of the present work was to synthesis polyamide 6 through anionic polymerization of ε-caprolactam in an internal mixer. The reaction time and the rheological properties of samples during the polymerization were studied. The samples were characterized by Thermo Gravimetry Analysis (TGA), Differential Scanning Calorimeter (DSC) and FT-IR spectrometer. The melt flow behavior and ...
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Polymerizable anionic wormlike micelles are obtained upon mixing the hydrotropic salt p-toluidine hydrochloride (PTHC) with the reactive anionic surfactant sodium 4-(8-methacryloyloxyoctyl)oxybenzene sulfonate (MOBS). Polymerization captures the cross-sectional radius of the micelles (approximately 2 nm), induces micellar growth, and leads to the formation of a stable single-phase dispersion of...
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چکیده ندارد.
Anionic Vinyl Polymerization
The concept of anionic polymerization was first developed by Ziegler and Schlenk in early 1910. Their pioneering work on the polymerization of diene initiated with sodium metal set the stage for the use of alkali metal containing aromatic hydrocarbon complexes as initiators for various α-olefins. In 1939, Scott and coworkers used for the first time the alkali metal complexes of aromatic hydroca...
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ژورنال
عنوان ژورنال: Polymer Journal
سال: 1981
ISSN: 0032-3896,1349-0540
DOI: 10.1295/polymj.13.1099